Estimation of the phosphate state of arable and fallow soils of different genesis according to indicators of phosphate buffering
DOI:
https://doi.org/10.31073/acss96-02Keywords:
soils, phosphate regime, phosphate-buffering, fertility, phosphorus accumulation, phosphorus mobilization, ironAbstract
The purpose of the article is to highlight the results of the experimental assessment of the phosphate state of soils of different genesis and the use of phosphate-buffering properties of the soil as indicators, and to identify the nature of the effect of iron on the behavior of phosphate ions. Sod-podzolic sandy loam and loamy soils with different moisture levels and different uses were the objects of the study. The place of research is the Volyn region of Ukraine. The methods of field, laboratory-model and laboratory-analytical studies are applied. Morphological characteristics of soils investigated in field conditions; laboratory-model studies were aimed at studying the behavior of phosphates under conditions of optimal and excessive moisture; laboratory-analytical methods were used to determine phosphate-buffering indicators and phosphate content in soil samples. It was determined that in soils in which regeneration processes are taking place, there is a deterioration of the phosphate regime, which is confirmed by indicators of phosphate buffering. It established that the application of fertilizers and meliorants contributes to the improvement of the phosphate-buffering capacity of soils, which is confirmed by the parameters of the buffer capacity and the coefficient of buffer asymmetry. It was found that the content of the granulometric fraction < 0.01 mm in the soil is an important factor in the effective functioning of buffer mechanisms: in sandy soil, the intensity factor, expressed as the negative decimal logarithm of the concentration of phosphate ions (pP), is 5.3 units, and in medium loam — 5.5 units. It has been confirmed that the accumulation of a significant amount of oxidized iron under reducing conditions leads to the deterioration of the phosphate state of the soil. It was experimentally established that in the version where iron is added, a decrease in the content of mobile forms of phosphorus is observed from 37.97 to 24.23 mg/kg according to the level of soil moisture maintained during composting.
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